The thirteenth chapter of Principles of Tribology by Wen Shizhu and Huang Ping is titled Anti-Wear Design and Surface Coating. Local material failure can lead to the failure of an entire machine, so improving the wear resistance of critical machine elements is important. The first part of anti-wear design is to establish a surface film (lubricant, adsorption or chemical). The second part is to select material pairs which will wear well together.
The fluid lubricant film is generally characterized by the film thickness ratio (lambda) which is the film thickness divided by combined roughness. There are many guidelines dependant on the contacting surfaces. In general cases lambda should be above 1.5. For high speeds or rough surfaces it should be above 2. For conformal contacts it should be between 2-5 and in some cases larger.
Viscosity is the most important factor when selecting a lubricating oil. As a part of this process consider the average and range of pressure and temperature experienced by the contact, so the lubricant will work adequately under all operating conditions. The second most important lubricant characteristic is oxidative stability which prevents the oil from deteriorating at elevated temperatures. Additives can be used to help modify these properties.
For a grease the base oil, thickener, and additives are all used to control film properties. The thickener or densifier controls temperature resistance, water resistance, hardness and fluidity. The base oil controls low temperature performance, viscosity and anti oxidation properties. Additives are used similarly to in oils.
Solid lubricants are used when a liquid or semi-solid lubricant cannot be used. A solid lubricated part will experience more friction and wear loss than with grease or oil. Materials used as solid lubricants should have low shear strength, thermal resistance and chemical resistance.
Selecting a seal and filter for a lubricating environment is important as well. Sealing is required to keep out particles which can reduce lubricant life by an order of magnitude. Particles cause problems when they embed in the surface and begin causing abrasive wear, when they roll around and cause plastic deformation leading to fatigue wear and when they roll around creating ridges which lead to adhesive wear.
Selecting a material depends on the primary wear mechanism. Higher hardness is nearly always beneficial for wear prevention. It can be increased through three different methods: mechanical processing, diffusion treatments, and coatings.
- For abrasive wear the natural hardness of material is most important because artificially increasing the hardness has a smaller effect on wear resistance. If there is impact by particles traveling parallel to the surface, hardness is important. If the particles are traveling perpendicularly to the surface, toughness is important. The hardness should be more than 1.4 times the hardness of third body particles.
- For adhesive wear low solid solubility is one of the most important factors in reducing wear. Brittle materials work better than plastic for the same reason. High melting temperature and high crystallization temperatures also reduce adhesion. High hardness and multiphase metals are also preferable to low hardness and single phase metals.
- For contact fatigue high hardness is important. 62 HRC is the optimal hardness because above that increased brittleness reduces life. It is best for there to be a slight difference between material hardnesses. Inclusions should be eliminated to have a clean material.
- For fretting conditions, materials resistant to adhesive wear perform the best.
- For corrosive wear materials which resist corrosion work best.
Surface coatings can be made of one or multiple layers of material added to the surface. Several coating processes are summarized briefly in this section of the book.
- Bead welding uses the welding process to add a layer about 1 mm thick. It is efficient but can cause cracking.
- Thermal spraying processes spray molten or semi-molten particles at the surface. There are three types: plasma, arc and flame spraying. This process works for very large parts.
- Slurry coatings are created by brushing onto the surface a solid-liquid mixture. Slurry coatings can be applied at low temperatures. One subcategory is slurry coating which consist of brushing, evaporating the liquid and then sintering. A second is glue coatings which are painted on and then solidify. A third is thermochemical reaction slurry coatings in which a compound in the slurry reacts chemically with the surface.
- Electro brush plating uses a graphite brush to move over the surface causing metal ions to diffuse onto the surface. The bond strength is based on the crystal structure at the interface.
- Plating can be either chemical or physical. Vacuum evaporation plating coating material evaporates in a vacuum and coats the surface. In sputtering particles bombard the coating source material releasing ions which form a thin film on the surface. Ion plating combines melting with an ion source and create strong bonds with the surface.
- Chemical vapor deposition has a gas which reacts with the surface and takes place at high temperatures.
When designing a surface the material properties and microstructure of the coating must be selected while considering the operational conditions. The coating material needs to be compatible with the substrate material. Applying the coating must be technically feasible. When selecting a method for applying a coating consider the material melting point, coating thickness required, bond strength and heat resistance of the substrate.
Evaluating coatings is also difficult. Tests should be carried out for a wide variety of properties.
- Visual appearance should be smooth, dense, and of uniform color. There should be no visible defects in the surface.
- The thickness can be measured with a microscopy of a cross section, by measuring width of the part before and after coating, or by using eddy current.
- Coating porosity is defined as the pores per unit area. It can be measured by massing the material with and without water or by spraying a part, weighing it, grinding it to its original dimensions and weighing it again.
- Bond strength can be measured in many different ways and can measure the adherence of the coating to itself or the coating to the substrate.
- Hardness can be measured using static or dynamic tests. Microhardness testing can find the hardness of a single particle. Hoffman scratch testing provides good correlation with wear resistance.
- Wear testing is often necessary because hardness is not a perfect predictor of wear.
- Fatigue can be tested using a4 point bending test
- Residual stress is related to the thermal expansion of the coating and substrate and can be measured with X-ray diffraction or a bending curvature test.