Film forming behavior of greases under starved and fully flooded EHL conditions

The performance of grease under starved conditions was investigated by researchers from Kluber.  Two lithium complex semi-synthetic greases were tested which differed only in their base oil viscosity. The greases were compared with their base oils.  Testing was carried out using an optical EHL rig manufactured by PCS Instruments.

Two primary testing protocols were used in this study.  The first was used to record a film thickness-velocity curve, run the contact in for two hours and then measure a second film thickness-velocity curve.  The second protocol was to run a contact at a constant speed of 1 m/s with the test being stopped at intervals to allow grease to flow back into the contact.

As velocity increased a grease in starved conditions went through several stages (from low to high velocity):

  1. Film thickness drop with increasing velocity at very low speeds.  Sometimes this stage did not occur because the velocity range did not extend low enough.  The inverse behavior is due to a thickener layer
  2. Increasing film thickness with velocity until a starvation point was reached.  The behavior is due to increasing oil entrainment.
  3. Film thickness decreases with velocity due to starvation.
  4. Increasing or flat film thickness.  This usually occurred around 1 m/s.  It must be due to grease reflow into the contact but the reasons for it are unknown.

The investigators found that starvation, the transition from phase 2 to 3, was controlled by the term (velocity x viscosity / load) and temperature.  However, the critical uv/W level can vary along with the film thickness it occurs at based on many factors.  Some of these factors include running time, lubricant viscosity, lubricant volume, temperature and other test conditions.

The base oils exhibited same behavior as the greases.  Even though oil can reflow more easily, it can also be flung out of the contact with less effort.  Interestingly, fully flooded greases experienced the same behavior as starved greases after having been run-in for a period of time.

The researchers also looked at the effect of the thickener and additive system on film thickness by calculating the ratio of the grease film thickness to base oil film thickness.  The thickener and additive systems increased film thickness at low speeds but were often detrimental at higher speeds.

It was postulated that the film thickness consists of three different layers:

  1. Solid-like layer of deposited thickener.  This was small in this study because of the non-reactive glass disk.
  2. Adsorbed layer of thickener and additive molecules
  3. Residual grease layer of thickener-rich high viscous material

Citation

  • Balasubramaniam Vengudusamy, Marius Kuhn, Michael Rankl & Reiner Spallek (2016) Film Forming Behavior of Greases Under Starved and Fully Flooded EHL Conditions, Tribology Transactions, 59:1, 62-71, DOI: 10.1080/10402004.2015.1071450
01 grease and base oil-initial and 2 hr
Starved behavior of the grease and base oil initially and after two hours of running.
02 grase and base oil uvW plot
Starved behavior of the grease and base oil initially and after two hours of running.
03 base oil
Starved behavior of the grease and base oil initially and after two hours of running.
04 hta ratio initial and 2 hr
Starved behavior of the grease and base oil initially and after two hours of running.
05 starvation regimes
Starved behavior of the grease and base oil initially and after two hours of running.
film layer composition
Starved behavior of the grease and base oil initially and after two hours of running.

Starved Grease Lubrication of Rolling Contacts

This study by Phillipa Cann of Imperial College investigated how the film thickness of grease evolves under starved conditions.  The tests were carried out with an optical elastohydrodynamic lubrication machine produced by PCS Instruments.  Tests were run under fully flooded and starved conditions and compared with one another.

Six greases were used in this study.  All of the greases had the same lithium thickener and paraffinic (mineral) base oil.  The greases were made with three different thickener percentages (5%, 9% and 15%) and two different base oil viscosities (30 and 200 cSt at 40 C).  Testing temperatures ranged from from 25 C to 80 C and velocities were between 0.005 and 1.0 m/s.

The fully flooded film thickness of the greases were measured first for baseline values.  The greases behaved as expected: linear on a log-log plot of film thickness and velocity (with some deviation at low speed where boundary lubrication effects played a role).  Then endurance tests were run under starved conditions and a gradual decline in film thickness was observed.  The raw data and the ratio between starved and fully flooded film thickness were both presented.  Tests were carried out to investigate the effects of grease ingredients, test conditions and oil separation.

Several conclusions were made about the variables tested.  Starvation increases with

  • Increased base oil viscosity
  • Increasing thickener content
  • Decreasing oil bleed
  • Increasing temperature
  • Decreasing temperature

Citation

  • P.M. Cann (1999) Starved Grease Lubrication of Rolling Contacts, Tribology Transactions, 42:4, 867-873, DOI: 10.1080/10402009908982294
01 Fully flooded behavior
Fully flooded film thickness for a grease.
02 Effect of thickener content on film thickness
Fully flooded film thickness for a grease.
03 Comparison starved versus fully flooded
Fully flooded film thickness for a grease.
04 relative-base oil viscosity
Fully flooded film thickness for a grease.
05 relative-temperature
Fully flooded film thickness for a grease.
06-relative speed
Fully flooded film thickness for a grease.